PINE DERIVATIVES MARKETING,INC. -- GUM TURPENTINE  -- 8010-00N008983
<pre>=====================  Product Identification  =====================

Product ID:GUM TURPENTINE
MSDS Date:11/22/1985
FSC:8010
NIIN:00N008983
=== Responsible Party ===
Company Name:PINE DERIVATIVES MARKETING,INC.
Address:3512-8 SILVERSIDE ROAD
City:WILMINGTON
State:DE
ZIP:19810
Country:US
Info Phone Num:302-478-6704
Emergency Phone Num:302-478-9768
CAGE:PINED
=== Contractor Identification ===
Company Name:PINE DERIVATIVES MARKETING,INC.
Address:3512-8 SILVERSIDE ROAD
Box:City:WILMINGTON
State:DE
ZIP:19810
Country:US
Phone:302-478-6704
CAGE:PINED

=============  Composition/Information on Ingredients  =============

Ingred Name:TURPENTINE
CAS:8006-64-2
RTECS #:YO8400000
Fraction by Wt: 100%
Other REC Limits:N/K 
OSHA PEL:100 PPM
ACGIH TLV:100 PPM; 9192

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE SUPP DATA
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE PREDISPOSITION TO PNEUMONIA
    AND CHRONIC NEPHRITIS,CHRONIC EXPOS CAN PRODUCE ALLERGENIC
    SENSITIZATION.CAN CAUSE DERMATITIS.MEANS LETHAL DOSE ADULT 4-6
    OZ.POSSIBLY TERATOGENIC EFFECTS EXIST FO R PREGNENT WOMEN(AIHA
    JOURNAL,1976,423-26).UPON MASSIVE EXPOS TO TURPENTINE,ATTN SHOULD
    BE DIRECTED TOWARD KIDNEY FUNCTN
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:IRRIT & DMGING.CAN CAUSE CONJUNCT OR
    CORNEAL BURNS.VAP CAN IRRIT EYES AT 175 PPM.SKIN:CAN CAUSE CHEM
    BURNS.CAN PENETRATE SKIN TO PRODUCE SYS EFFECTS.INGEST:CAN PRODUCE
    NAUSEA,SERIOUS ILLNESS OR E VEN DEATH.INHAL:IRRIT.CAN PRODUCE
    HDACH,DIZZINESS,VERTIGO,CHEST PAIN,BRONCH.PULM
    EDEMA,CYANOSIS,NARCOSIS & ACCEL PULSE.
Medical Cond Aggravated by Exposure:N/K 

=======================  First Aid Measures  =======================

First Aid:EYES:IMMED FLUSH W/ RUNNING WATER FOR AT LEAST 15 MIN.GET MED
    ATTN IMMED.SKIN:REMOVE CONTAM CLTHG PROMPTLY.LAUNDER BEFORE
    REUSE.GET MED ATTN IF IRRIT PERSISTS,INGEST:GET MED HELP PROMPTLY
    STOMACH PUMP ING & LAVAGE MAY BE REQUIRED.GIVE EDIBLE OIL/WHITE
    MINERAL OIL TO DRINK.DO NOT INDUCE VOMIT.ASPIRATION A HAZ IF VOMIT
    OCCURS.INHAL:MOVE TO FRESH AIR.GET MED ATTN FOR EXCESS EXPOS OR IF
    IRRIT PERSISTS.

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:91F.33C
Lower Limits:0.(% BY VOL
Upper Limits:N/K 
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL OR FOAM.WATER MAY BE
    INEFFECTIVE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
    .USE WATER TO COOL FIRE-EXPOSED CNTNRS.DIKE AREA TO PREVENT RUNOFF.
Unusual Fire/Explosion Hazard:WHEN HEATED,MATERIAL IS A MODERATE FIRE
    AND EXPLOSION HAZARD,HAZARDOUS DECOMPOSITION PRODUCTS:CARBON
    MONOXIDE AND/OR CARBON DIOXIDE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:PROVIDE ADEQ EXPLO PROOF VENTIL TO REMOVE
    FUMES FROM SPILL AREA.WHERE EXPOS LEVEL IS NOT KNOWN,WEAR NIOSH
    APPRVD POS PRESS SCBA & FULL PROT EQUIP.PICK UP W/ ABSORB MATL &
    PLACE IN WASTE DISPOS CNTNR.F LUSH AREA W/ H*20.AVOID BRTHG OF VAP
    & CONT W/ LIQ
Neutralizing Agent:N/K 

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN WELL-VENT,COOL DRY AREA AWAY
    FROM SOURCES OF HEAT & IGNIT.NO SMOKING IN STOR/USE AREAS.AVOID
    OPEN FLAME.AVOID BRTHG OF VAP & SKIN & EYE CONT.
Other Precautions:USE OF BONDING & GROUNDING OF CNTNRS FOR ATIC
    SPARKS.EMPTIED CNTNRS RETAIN VAP & PRODUCE RESIDUE.WARNING
    STATEMENTS:FLAMM LIQ & VAP.HARMFUL IF INHALED.IRRIT TO SKIN &
    EYES.PENETRATES SKIN.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
    EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
    CONCENTRATION BELOW TLV .
Protective Gloves:IMPERVIOUS RUBBER.
Eye Protection:CHEMICAL WORKERS GOGGLES (
Other Protective Equipment:PROVIDE EYE BATH AND SAFETY SHOWER IN AREA
    OF USE.
Work Hygienic Practices:N/K 
Supplemental Safety and Health
AUTOIGNIT TEMP:476F,247C.VP:4 MMHG @ 68F,20C.SATURATION IN AIR:0.5% BY
    VOL @ 68F,20C & 760 MMHG REF IND:473 & 68F,20C.LD50-LC50 MIX:A &
    B-PINENE:LD50 RAT ORAL 3700->5000 MG/KG (ACUTE).TURPENTINE:LDLO 
    HUMAN ORAL 500 MG/KG,LC50 HUMAN INHAL 175 PPM (IRRITANT EFFECTS).

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:311-345F
Melt/Freeze Pt:M.P/F.P Text:N/K 
Decomp Temp:Decomp Text:N/K 
Vapor Pres:SEE SUPP
Vapor Density:4.84 AIR=1
Spec Gravity:0.8650 (H*20@1)
Evaporation Rate &amp; Reference:N/K 
Solubility in Water:0.023% BY WT. 20-25C
Appearance and Odor:CLEAR,COLORLESS LIQ W/ CHARACTERISTIC PINACEOUS
    ODOR.PERCEPTION THRESHOLD:<75PP
Percent Volatiles by Volume:+99

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ACIDS OR ACIDIC MATERIAL AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:MATL CAN UNDERGO AUTOOXIDATION IN AIR &
    GENERATE HEAT WHICH CAN BUILD UP IN CONFINED SPACES CAUSING
    CPONTANEOUS COMBUST.
Hazardous Decomposition Products:CARBON MONOXIDE AND/OR CARBON DIOXIDE.
Conditions to Avoid Polymerization:MAY OCCUR FROM CONTAMINATION WITH
    ACIDS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
    FEDERAL,STATE AND LOCAL REGULATIONS .BURNING IS RECOMMENDED FOR
    WASTE DISPOSAL USING AN APPROVED INCINERATOR.

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